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Synthesis of visible light active surfaces

Titanium dioxide (TiO2) films and coatings have been shown to be very effective in photo-oxidation applications due to their photocatalytic properties. However, due to the large band gap energy of TiO2, conventional coatings can only be activated under ultraviolet light, which represents only a small fraction (<5%) of incident solar light.

The aim of this project is to prepare a nitrogen-doped titanium dioxide coating using the sol-gel technique. Surface and bulk modification by anions changes the band gap of the titanium dioxide and enables it to utilise more of the visible spectrum, thereby increasing its efficiency under visible light. The doped titanium dioxide will be examined with respect to crystal structure, composition, flat band potential, isoelectric point, and photocatalytic activity.

 

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Modified: 10 June 2008
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