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Development and optimisation of a novel optical fibre photoreactor for photocatalytic applications

TiO2 nanoparticles are renowned for their excellent photocatalytic activity and capability to mineralise organic and inorganic pollutants to H2O and CO2 in air and water. Photocatalytic efficiency depends on both photocatalyst characteristics and the extent to which the particles are illuminated in a photoreactor. Optical fibres are a means of improving the latter issue.

In this work, Computational Fluid Dynamics (CFD) simulation was used to predict light distribution in a photoreactor space occupied by TiO2-coated glass beads irradiated by means of an optical fibre. In addition, the degradation of oxalic acid in the reactor was also modelled and the results were compared to experimental data.

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